2026-04-11 19:00:27
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圖片:太陽能誘導的直接使用生物質發電的混合燃料電池。這種燃料電池依賴於POM催化劑(小瓶中所示),當與光發生反應,它改變了顏色。
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在這個新係統中,生物質被碾碎,並與多金屬氧酸鹽(POM)催化劑溶液混合在一起,然後暴露在太陽光下或進行加熱。作為一種光化學和熱化學催化劑,POM既可用作氧化劑又可作為電荷載體。POM在(zai)光(guang)和(he)熱(re)輻(fu)射(she)下(xia)氧(yang)化(hua)生(sheng)物(wu)質(zhi),並(bing)將(jiang)電(dian)荷(he)從(cong)生(sheng)物(wu)質(zhi)運(yun)送(song)到(dao)燃(ran)料(liao)電(dian)池(chi)的(de)陽(yang)極(ji)。這(zhe)些(xie)電(dian)子(zi)隨(sui)後(hou)被(bei)輸(shu)送(song)到(dao)陰(yin)極(ji),並(bing)最(zui)終(zhong)通(tong)過(guo)外(wai)部(bu)電(dian)路(lu)被(bei)氧(yang)化(hua)產(chan)生(sheng)電(dian)。
研究人員解釋,如果在室溫下混合生物質和催化劑,它們是沒有反應的。但是將它們暴露在光或熱下,反應開始了。POM引(yin)入(ru)了(le)一(yi)個(ge)中(zhong)間(jian)步(bu)驟(zhou),因(yin)為(wei)生(sheng)物(wu)質(zhi)不(bu)能(neng)直(zhi)接(jie)接(jie)觸(chu)到(dao)氧(yang)。該(gai)係(xi)統(tong)具(ju)有(you)很(hen)多(duo)優(you)點(dian),它(ta)結(jie)合(he)光(guang)化(hua)學(xue)和(he)太(tai)陽(yang)能(neng)熱(re)降(jiang)解(jie)生(sheng)物(wu)質(zhi)在(zai)一(yi)個(ge)單(dan)一(yi)的(de)化(hua)學(xue)過(guo)程(cheng),並(bing)引(yin)導(dao)了(le)高(gao)太(tai)陽(yang)能(neng)轉(zhuan)化(hua)和(he)有(you)效(xiao)生(sheng)物(wu)質(zhi)降(jiang)解(jie)。這(zhe)個(ge)過(guo)程(cheng)中(zhong)沒(mei)有(you)使(shi)貴(gui)金(jin)屬(shu)作(zuo)為(wei)陽(yang)極(ji)催(cui)化(hua)劑(ji),因(yin)為(wei)燃(ran)料(liao)的(de)氧(yang)化(hua)反(fan)應(ying)是(shi)由(you)POM溶液催化的。最後,由於POMshihuaxuewendingde,hunheranliaodianchikeyishiyongweichunhuadejuheshengwuzhierbuyongdanxinguijinshuyangjizhongdu。gaixitongkeyishiyongshuirongxingshengwuzhi,huoyoujicailiaoxuanfuzaiyetizhong。zaishiyanzhong,ranliaodianchiyunxinglechangda20小時,這表明POM催化劑不需要進一步處理就可以重複利用。
在論文中,研究人員報告其最大功率密度為每平方厘米0.72毫瓦,這比基於纖維素的微生物燃料電池高近100倍。科學家們認為當這一過程優化後,其輸出量還可以提高五到十倍。