過渡金屬材料結構設計用於高效電催化反應研究進展

據materialsview報道：由you於yu傳chuan統tong化hua石shi能neng源yuan的de過guo度du使shi用yong所suo造zao成cheng的de環huan境jing汙wu染ran和he能neng源yuan危wei機ji問wen題ti日ri益yi威wei脅xie著zhe當dang今jin人ren類lei社she會hui的de生sheng存cun與yu發fa展zhan，開kai發fa下xia一yi代dai清qing潔jie可ke再zai生sheng能neng源yuan係xi統tong受shou到dao人ren們men越yue來lai越yue多duo的de關guan注zhu。電dian化hua學xue能neng源yuan存cun儲chu和he轉zhuan換huan係xi統tong
，例li如ru燃ran料liao電dian池chi，金jin屬shu空kong氣qi電dian池chi，電dian解jie水shui器qi件jian以yi及ji二er氧yang化hua碳tan還hai原yuan技ji術shu成cheng為wei應ying對dui環huan境jing和he能neng源yuan危wei機ji的de重zhong要yao手shou段duan。由you於yu此ci類lei係xi統tong中zhong所suo涉she及ji的de電dian化hua學xue反fan應ying的de動dong力li學xue惰duo性xing，電dian催cui化hua劑ji的de性xing能neng成cheng為wei影ying響xiang能neng源yuan與yu轉zhuan換huan器qi件jian最zui終zhong性xing能neng的de最zui重zhong要yao因yin素su。鉑bo
、釕、銥、金等傳統貴金屬催化劑雖具有優異的催化性能

，但其高昂的價格、guodidechuliangyijijiaochadeyunxingwendingxingyanzhongxianzhileqizaixinyidaidianhuaxuenengyuanxitongzhongdeguangfanyingyong。jinxienianlai

，weilejiangdiduiguijinshudiancuihuajideyilai，kaifayiguodujinshuweijichudediancuihuajiyongyudianhuaxuefanyingyinqileyanjiuzhemendeguangfanguanzhu。

通過對近年研究工作的分析和總結
，湖南大學王雙印教授與新加坡南洋理工大學王昕教授合作在名為“Rational Design of Transition Metal-Based Materials for Highly Efficient Electrocatalysis”的綜述文章中
，係統總結了對於過渡金屬電催化劑的常見設計方案及其獲得高催化活性的原理。該綜述文章從創造更多催化活性位點、提高活性中心利用率、調節材料電子構型、提高導電性、以及控製材料晶麵生長等方麵，詳細闡述了合理地材料設計對於提高材料電催化活性（電催化氧還原ORR、氧析出OER、氫析出HER、二氧化碳還原CO2RR等）的de重zhong要yao作zuo用yong及ji原yuan理li。文wen章zhang為wei研yan究jiu者zhe們men在zai過guo渡du金jin屬shu電dian催cui化hua材cai料liao設she計ji方fang麵mian提ti供gong了le深shen刻ke指zhi導dao作zuo用yong。文wen末mo


，作zuo者zhe對dui過guo渡du金jin屬shu電dian催cui化hua劑ji研yan究jiu未wei來lai的de發fa展zhan趨qu勢shi以yi及ji相xiang應ying的de機ji遇yu和he挑tiao戰zhan進jin行xing了le展zhan望wang
，為wei其qi在zai新xin一yi代dai能neng源yuan存cun儲chu和he轉zhuan換huan係xi統tong中zhong的de應ying用yong提ti供gong了le參can考kao。

該綜述文章“Rational Design of Transition Metal-Based Materials for Highly Efficient Electrocatalysis”在線發表在Small Methods (DOI: 10.1002/smtd.201800211)上。